Volume-12 (03/2006)

Measuring the surface free energy of human skin

Author: Dr. Frank Thomsen, KRÜSS GmbH

 

Abstract


Previously the wetting properties of cosmetic products could only be determined when sufficient "helping hands" were available. Tests were carried out which in the product was applied to the skin and the result then assessed. It would be helpful if a prediction about the wettability on the skin could be made in advance, particularly as interactions between the various additives make the behavior more complicated. This gap in our knowledge can now be closed by making contact angle measurements with the DSA100.


Method


Human skin, just like any other surface, has a specific energy that can be measured. And it is just this physical property that, in combination with the surface tension of the cosmetic product, is responsible for its wettability.

However, a single energy value for the human skin is not enough. Various skin types must also be taken into account: skin can be dry, greasy, normal or even mixed. If the energy profiles of all these skin types are known then the wetting behavior with various liquids can be predicted. This ensures that different cosmetics can be perfectly matched to the particular user.




Schematic diagram of a sessile drop
Fig. 1: Schematic diagram of a sessile drop





Experimental


Both Owens/Wendt and Fowkes describe the relationship between the contact angle on a solid surface and the polar and disperse fractions σD and σP of the surface tensions of the two phases:



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With the aid of a drop shape analysis system contact angles are determined on the skin for different liquids. The surface free energy can then be determined directly from these values, provided that the polar and disperse fractions of the liquids are known.


A collection of data for all skin types drawn up in this way makes it possible to selectively alter the formulation of cosmetics by making use of molecular parameters such as polar behavior. This means that the number of measurements that have to be carried out on volunteers can be dramatically reduced.


Drop shape analysis system DSA100
Fig. 2: Drop shape analysis system DSA100





Result



The following table shows the differences in energy resulting from different degrees of greasiness of the skin:



Skin not degreased

Skin degreased

Surface free energy (mN/m)

43.7

32.9

Polar fraction (mN/m)

8.0

1.6

Disperse fraction (mN/m)

35.7

31.3



Tab. 1: Surface free energies of two skin types


If the polar fractions of the surface tension are plotted against the disperse fractions then the result is the “wetting envelope”, which is shown here using non-degreased skin as an example. (see Figure 3). All liquids whose data lie beneath the curve will provide complete wetting



Wetting envelope for non-degreased forehead skin
Fig. 3: Wetting envelope for non-degreased forehead skin




Summary

 


With the determination of the surface free energy of human skin only the surface tension components of the liquids involved are required to permit reliable statements to be made about the wetting behavior for various types of skin.



 

Literature

 

C. Rulison: Two-Component Surface Energy Characterization as a Predictor of Wettability and Dispersability. KRÜSS Application Note #213 (2000).

A. Mavon, H. Zahouani, D. Redoules, P. Agache, Y. Gall, Ph. Humbert: Sebum and Stratum Lipids Increase Human Skin Surface Free Energy as determined from Contact Angle Measurements: A Study on two Anatomical Sites. In: Colloids and Surfaces B: Biointerfaces. Vol 8, 1997. 147-155.

D.K. Owens, R. C. Wendt. In: Jour. Applied Polymer Sci. 13,1741 (1969).

F.M. Fowkes. In: Industrial and Engineering Chemistry, 56, 12, 40 (1964).