• Automotive varnishing

    Automotive varnishing

Adhesion on metals

Contact angle and surface tension for the processing of metal surfaces

When metals are processed, for example when bonding or painting, they come into adhesive contact with other substances. Here, the usually high surface free energy of metals is a favorable condition for good wetting and secure bonding. However, cleaning and, with some metals, also activation are necessary pre-treatment steps for optimizing the coating and bonding process. Our contact angle and surface tension measuring instruments undertake quality assurance tasks at the pre-treatment stage and provide measuring results for optimizing coating materials.

Quality assurance of cleaning solutions

Adhesion on metals is significantly reduced by adsorbed dirt, as a result of which surface contact is usually preceded by cleaning. Cleaning solutions often contain surfactants which reduce the surface tension, improving wetting and thus mobilizing hydrophobic substances.

Our tensiometers measure the surface tension and characterize the efficiency of surfactants based on the critical micelle concentration (CMC). This information helps in the choice and dosage of surfactant.

The surfactant content of the cleaning solution reduces during the process due to adsorption at the surface, thus necessitating regular re-dosing. In order to check the present surfactant content it is possible to measure the dynamic surface tension, which, in contrast to static surface tension, depends on the surfactant content even in the high concentration range. For this purpose, a calibration curve is produced with our stationary Bubble Pressure Tensiometer – BP100 laboratory unit. This is used as the basis for determining the active ingredient content on site using our Bubble Pressure Tensiometer – BP50 mobile instrument.

Checking the cleaned metal surface

Checking the metal surface before bonding or coating is another important step in ensuring quality. Here, the wettability, which is measured by our drop shape analysis instruments based on the contact angle, is used as a quality criterion. The homogeneity and quality of cleaning is indicated by a small water contact angle which should be as uniform as possible over the entire surface. Our Mobile Surface Analyzer – MSA mobile measuring instrument enables non-destructive checking to be carried out on site on surfaces of any size.

Measurement of surface free energy, adhesion and roughness

Some metals, for example aluminum or magnesium, are coated with a passivating oxide layer and require activating treatment before adhesive contact. Titanium as a prosthesis material is also pre-treated in order to improve biocompatibility due to the increased adhesion of biogenic materials, for example collagen. The various treatment methods effect an increase in the surface free energy or roughness, as a result of which both the wettability and the adhesion are improved.

The surface free energy can be measured with our measuring instruments based on the contact angle with several liquids. In doing so, both the polar and dispersive fraction of the surface free energy are determined. Combined with measurement of the surface tension of the coating substance, this enables the work of adhesion to be determined as a measure of the adhesion. By measuring the adjacent phases separately, it is possible to match the composition of the coating substance to the pre-treatment process.
The effect of roughness on the wettability can be seen when the contact angle during wetting (advancing angle) is compared with the contact angle when de-wetting (receding angle).

KRÜSS Application Reports

AR264: Light metal, but difficult to bond

Aluminum alloys, which in vehicle manufacturing are prepared for bonding in conversion baths, are investigated. With different alloys, dwell time and temperature have different effects on the measured surface free energy.